Kazuyuki Tatsumi


Professor Kazuyuki Tatsumi, PhD

巽和行 博士,教授





Scientific Career

1971  B.Sc. Osaka University

1976  Ph.D. Osaka University

1977  Postdoctoral Fellow, Texas A&M University (USA, with Prof. Minoru Tsutsui)

1979  Postdoctoral Fellow, Cornell University (USA, with Prof. Roald Hoffmann)

1982  Assistant Professor, Facul ty of Science, Osaka University

1991  Associate Professor, Faculty of Engineering Science, Osaka University

1994  Professor, Department of Chemistry, Faculty of Science, Nagoya University

1998  Professor, Research Center for Materials Science, and Department of Chemistry, Graduate School of Science, Nagoya University

2013- Honorary Professor, Nagoya University

2013- Designated Professor, Research Center for Materials Science, Nagoya University

2014- Member, The Japan Academy

2019- Disitinguished Chair Professor, Tongji University

Scientific Activities and Professional Recognitions

1.  Ordinary Member: Executive Board of International Council for Science (2014- )(国际科学理事会十位执行委员之一)

2.  Member, The Japan Academy (2014- ) (日本学士院院士)

3.  Program Officer: Japanese Society for the Promotion of Science (2013- )(日本学术振兴会程序负责人)

4.  Vice-Chair of Section III, Science Council of Japan (2013-2014)(日本科学理事会第三委员会副主席)

5.  President, IUPAC (2012-2013)(全球最大最权威的化学学术组织-国际纯粹与应用化学联合会主席)

6.  Head Investigator: Grant-in-Aid for Specifically Promoted Research of MEXT (Japan) Bioinorganic Chemistry of Oxidoreductases having UniqueActive Site Clusters (2011-2016)

7.  Vice President (President-elected), IUPAC (2010-2011)

8.  Council Member: Science Council of Japan (2008-2014)

9.  President: Division II (Inorganic Chemistry Division), IUPAC (2008-2009)

10.President: Organometallic Division, The Kinki Chemical Society, Japan (2007-2009)

Awards and Honors

1.  Corresponding Member: Nordrhein-WestfälischenAkademie der Wissenschaften und der Künste (2015)

2.  Honorary Member, The Chemical Society of Japan (2015)

3.  The Luigi Sacconi Memorial Lecture in Chemistry, Firenze, Italy (2013)

4.  The Japan Academy Prize (2013)

5.  The Prize for Science and Technology: The Commendation for Science and Technologyby the Ministry of Education, Culture, Sports, Science and Technology (2013)

6.  CUSO Lectureship, Switzerland (2011)

7.  The Eugen and IlseSeibold Prize, DFG, Germany (2011)

8.  Honorary Doctorate, University of Münster, Germany (2011)

9.  Frontiers in Chemistry Lecturer, Texas A&M University, USA (2010)

10.The Chemical Society of Japan Award (2006)

11.Humboldt Award, Alexander von Humboldt Foundation, Germany (2004)

Research Interests

1. Bioinorganic Chemistry of Oxidoreductases such as Nitrogenase, Hydrogenase, Acetyl-CoA Synthase, CO-Dehydrogenase, and Oxygen-Evolving Center of PSII

2. Organometallic Chemistry of Coordinatively Unsaturated Transition Metal Complexes



Research Publications

  1. Synthesis of an All-Ferric Cuboidal Cluster [FeIII4S4(SAr)4], G. Moula, T. Matsumoto, M. E. Miehlich, K. Meyer, and K. Tatsumi*, Angew. Chem. Int. Ed., 2018, 57, 11594-11597.

  2. Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofacto, K. Tanifuji, N. Sickerman, C. C. Lee, T. Nagasawa, K. Miyazaki, Y. Ohki*, K. Tatsumi*, Y. Hu*, and M. W. Ribbe*, Angew. Chem. Int. Ed., 2016, 55, 15633-15636.

  3. Coupling of an N-Heterocyclic Carbene on Iron with Alkynes Forming 5-Cyclopentadienyl-Diimine Ligand, T. Hatanaka, Y. Ohki*, and K. Tatsumi*, Angew. Chem. Int. Ed., 2014, 53, 2727-2729.

  4. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane, T. Stahl, K. Müther, Y. Ohki*, K. Tatsumi*, and M. Oestreich*, J. Am. Chem. Soc., 2013, 135, 10978-10981.

  5. Cooperative Catalytic Activation of Si-H Bonds by a Polar Ru-S Bond: Regioselective Low-Temperature C-H Silylation of Indoles under Neutral Conditions by a Friedel-Crafts Mechanism, H. F. T. Klare, M. Oestreich*, J. Ito, H. Nishiyama, Y. Ohki*, and K. Tatsumi*, J. Am. Chem. Soc., 2011, 133, 3312-3315.

  6. Synthetic analogues of [Fe4S4(Cys)3(His)] in hydrogenases and [Fe4S4(Cys)4] in HiPIP derived from all-ferric [Fe4S4{N(SiMe3)2}4, Y. Ohki, K. Tanifuji, N. Yamada, M. Imada, T. Tajima, and K. Tatsumi*, Proc. Natl. Acad. Sci. USA, 2011, 108, 12635-12640.

  7. A model for the CO-inhibited form of [NiFe] hydrogenase: synthesis of (CO)3Fe(μ-StBu)3Ni{SC6H3-2;6-(mesityl)2} and reversible CO addition at the Ni site, Y. Ohki, K. Yasumura, M. Ando, S. Shimokata, and K. Tatsumi*, Proc. Natl. Acad. Sci. USA, 2010, 107, 3994-3997.

  8. Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster, Y. Ohki*, M. Imada, A. Murata, Y. Sunada, S. Ohta, M. Honda, T. Sasamori, N. Tokitoh, M. Katada, and K. Tatsumi*, J. Am. Chem. Soc., 2009, 131, 13168-13178.

  9. C-H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene, Y. Ohki*, T. Hatanaka, and K. Tatsumi*, J. Am. Chem. Soc., 2008, 130, 17174-17186.

  10. Reversible Heterolysis of H2 Mediated by an M-S(thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase, Y. Ohki*, M. Sakamoto, and K. Tatsumi*, J. Am. Chem. Soc., 2008, 130, 11610-11611.

  11. A Functional Hydrogenase Model: Reversible Interconversion of H2 and H2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium-Germanium Complex, T. Matsumoto, Y. Nakaya, N. Itakura, and K. Tatsumi*, J. Am. Chem. Soc., 2008, 130, 2458-2459.

  12. Heterolytic Dihydrogen Activation by a Sulfido- and Oxo-Bridged Dinuclear Germanium-Ruthenium Complex, T. Matsumoto, Y. Nakaya, and K. Tatsumi*, Angew. Chem. Int. Ed., 2008, 47, 1913-1915.

  13. Thiolate-bridged dinuclear iron(tris-carbonyl)–nickel complexes relevant to the active site of [NiFe] hydrogenase, Y. Ohki, K. Yasumura, K. Kuge, S. Tanino, M. Ando, Z. Li, and K. Tatsumi*, Proc. Natl. Acad. Sci. USA, 2008, 105, 7652-7657.

  14. Synthesis of New [8Fe-7S] Clusters: A Topological Link Between the Core Structures of P-Cluster, FeMo-co, and FeFe-co of Nitrogenases, Y. Ohki, Y. Ikagawa, and K. Tatsumi*, J. Am. Chem. Soc., 2007, 129, 10457-10465.

  15. Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)2(CN)2 (SCH2CH2CH2S)Ni(S2CNR2)] Modeling the Active Site of [NiFe] Hydrogenase, Z. Li, Y. Ohki, and K. Tatsumi*, J. Am. Chem. Soc., 2005, 127, 8950-8951.

  16. A half-sandwich ruthenium(II) complex containing a coordinatively unsaturated 2,6-dimesitylphenyl thiolate ligand, Y. Ohki, H. Sadohara, Y. Takikawa, and K. Tatsumi*, Angew. Chem. Int. Ed., 2004, 43, 2290-2293.

  17. Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes, Y. Ohki, N. Matsuura, T. Marumoto, H. Kawaguchi, and K. Tatsumi*, J. Am. Chem. Soc., 2003, 125, 7978-7988.

  18. Synthesis of the P-Cluster Inorganic Core of Nitrogenases, Y. Ohki, Y. Sunada, M. Honda, M. Katada, and K. Tatsumi*, J. Am. Chem. Soc., 2003, 125, 4052-4053.

  19. Unusual Coordination Modes of Arylthiolates in Mo{5-SC6H3-2,6-(SiMe3)2}{7-SC6H3-2,6-(SiMe3)2}, T. Komuro, T. Matsuo, H. Kawaguchi*, and K. Tatsumi*, J. Am. Chem. Soc., 2003, 125, 2070-2071.

  20. Spontaneous Formation of a Diamond-crown Structure of Re8 Polyselenide and a Cage Structure of Re3 Polytelluride, G. X. Jin, Y. Arikawa, and K. Tatsumi*, J. Am. Chem. Soc., 2001, 123, 735-736.

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